In that case be sure to check out the rest of the Shadow of the Colossus soundtrack. It's excellent. Here's some more suggestions:
Ratchet and Clank 2 - Swampy Boss (
http://www.youtube.com/watch?v=XNGItvTDFGM)
Final Fantasy X - Decisive Battle (
http://www.youtube.com/watch?v=NvhFUDWZls8&p=EE9B8E4750CB344A&playnext=1&index=86)
Final Fantasy Tactics - Intersection (
http://www.youtube.com/watch?v=rVrQv36YFgg)
Metal Gear Solid - Duel (
http://www.youtube.com/watch?v=SSdERzvgUf0)
Metal Gear Solid 2 - Kill Me Now! (
http://www.youtube.com/watch?v=GSfDrAy6DVo&feature=related)
Metal Gear Solid 2 - Yell "Dead Cell" (
http://www.youtube.com/watch?v=cgxCMMEjpGI)
Dragon Quest VIII - Great Battle In The Vast Sky (
http://www.youtube.com/watch?v=_VkVnwfLsiw)
Dragon Quest VIII - Defeat The Enemy (
http://www.youtube.com/watch?v=meygA7NcuBg&feature=related)
Final Fantasy VI - The Decisive Battle (
http://www.youtube.com/watch?v=BkcODYXxLw4) (Not the original version but I can't find it in good quality since Silvagunner's channel got taken down, but this is the next best thing)
Kingdom Hearts 2 - Darkness of the Unknown (
http://www.youtube.com/watch?v=Qz2nEoSYgzc)
Demon's Souls - Maiden Astraea (
http://www.youtube.com/watch?v=K-rNVnrFQDg)
Portal - You Can't Escape You Know (
http://www.youtube.com/watch?v=5RThhEK2srk)
Valkyria Chronicles - Decisive Battle (
http://www.youtube.com/watch?v=_suAWCkeg2Y)
Valkyria Chronicles - Final Battle (
http://www.youtube.com/watch?v=ozI4AcYrC08&feature=related)
I can't think of any other boss themes right now. I guess I could post boss themes from Final Fantasy and other RPG's all day, but I'd like some more diversity.